|
|
2-methylbutanoyl-CoA + flavin <=> tigloyl-CoA + reduced_flavodoxin + H+
|
1.3.8.5
2-methyl-branched-chain-enoyl-CoA reductase
1.3.99.12
2-methylacyl-CoA dehydrogenase
|
–
–
|
|
| |
BRENDA:
BR1200
KEGG:
R03169
|
|
|
|
2-methylbutanoyl-CoA + acceptor <=> tigloyl-CoA + reduced_acceptor
|
1.3.8.1
short-chain acyl-CoA dehydrogenase
1.3.99.12
2-methylacyl-CoA dehydrogenase
|
–
–
|
|
| |
BRENDA:
BR36850
KEGG:
R03173
|
|
|
|
2-methylbutanoyl-CoA + 5 methylmalonyl-CoA + 7 malonyl-CoA + 9 NADPH + 9 H+ <=> 6,8a-Seco-6,8a-deoxy-5-oxoavermectin_''''2a''''_aglycone + 12 CO2 + 13 CoA + 5 H2O + 9 NADP+
|
not assigned
|
–
|
K
|
| |
KEGG:
R06480
|
|
|
|
2-methylbutanoyl-CoA + 5 methylmalonyl-CoA + 7 malonyl-CoA + 9 NADPH + 9 H+ <=> 6,8a-Seco-6,8a-deoxy-5-oxoavermectin_''''1a''''_aglycone + 12 CO2 + 13 CoA + 6 H2O + 9 NADP+
|
not assigned
|
–
|
K
|
| |
KEGG:
R06481
|
|
|
|
2-methylbutanoyl-CoA + phosphate <=> CoA + 2-methylbutanoyl_phosphate
|
2.3.1.19
phosphate butyryltransferase
|
–
|
|
| |
BRENDA:
BS454935
|
|
|
|
2-methylbutanoyl-CoA + phosphate <=> 2-methylbutanonyl_phosphate + CoA
|
2.3.1.19
phosphate butyryltransferase
|
–
|
|
| |
BRENDA:
BS454934
|
|
|
|
3-methyl-2-oxopentanoate + CoA + oxidized_ferredoxin <=> 2-methylbutanoyl-CoA + CO2 + reduced_ferredoxin
|
1.2.7.7
3-methyl-2-oxobutanoate dehydrogenase (ferredoxin)
|
–
|
B
|
| |
BRENDA:
BS359414
|
|
|
|
tigloyl-CoA + NADPH <=> 2-methylbutanoyl-CoA + NADP+
|
1.3.1.8
acyl-CoA dehydrogenase (NADP+)
|
–
|
|
| |
BRENDA:
BS258636
|
|
|
|
2-methylbutanoyl-CoA + malonyl-[acyl-carrier_protein] <=> 3-oxo-4-methyl-hexanoyl-[acyl-carrier_protein] + CoA + CO2
|
2.3.1.180
beta-ketoacyl-[acyl-carrier-protein] synthase III
|
–
|
|
| |
BRENDA:
BS381010
|
|
|
|
2-methylbutanoyl-CoA + electron_acceptor <=> tigloyl-CoA + reduced_acceptor
|
1.3.8.1
short-chain acyl-CoA dehydrogenase
|
–
|
|
| |
BRENDA:
BS395572
|
|
|
|
ATP + 2-methylbutanoate + CoA <=> ADP + phosphate + 2-methylbutanoyl-CoA
|
6.2.1.13
acetate---CoA ligase (ADP-forming)
6.2.1.B11
|
–
–
|
B
|
| |
BRENDA:
BS425944
|
|
|
|
ATP + methyl_butyrate + CoA <=> AMP + diphosphate + 2-methylbutanoyl-CoA
|
6.2.1.44
3-(methylthio)propionyl---CoA ligase
|
–
|
|
| |
BRENDA:
BS428376
|
|
|
|
ATP + 2-methylbutanoate + CoA <=> AMP + diphosphate + 2-methylbutanoyl-CoA
|
6.2.1.2
medium-chain acyl-CoA ligase
|
–
|
|
| |
BRENDA:
BS428212
|
|
|
|
2-methylbutanoyl-CoA + FAD <=> FADH2 + tigloyl-CoA
|
1.3.8.4
isovaleryl-CoA dehydrogenase
1.3.8.7
medium-chain acyl-CoA dehydrogenase
1.3.99.12
2-methylacyl-CoA dehydrogenase
|
–
–
–
|
|
| |
SABIO-RK:
3002
|
|
|
|
NAD+ + 3-methyl-2-oxopentanoate + CoA <=> CO2 + H+ + NADH + 2-methylbutanoyl-CoA
|
1.2.4.4
3-methyl-2-oxobutanoate dehydrogenase (2-methylpropanoyl-transferring)
|
–
|
|
| |
SABIO-RK:
3001
|
|
